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Effects of mixing protocol on morphology and properties of PA6/ABS blends compatibilized with MMA-MA

The effect of different mixing protocols in the preparation of PA6/ABS/MMA-MA (57.5/37.5/5 wt %) blends on their morphological, rheological, thermal, thermomechanical, and mechanical behavior were studied. Despite the second-phase size reduction due to copolymer incorporation, mixing sequence seems... Full description

Contained in: Journal of Applied Polymer Science Vol. 133, No. 27 (2016), p. 43612/1-8
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Links: Additional Link (dx.doi.org)
ISSN: 1097-4628
Additional Keywords: COPOLYMER
INKORPORIERUNG
PHASENVERMITTLER
POLYAMID
STOFFGEMISCH
VERTRAEGLICHMACHEN
ZAEHFESTIGKEIT
DOI: 10.1002/app.43612
Notes: Copyright: Metadaten: TEMA, Copyright WTI-Frankfurt eG
Copyright: (C) Alle Rechte beim Herausgeber
Physical Description: 8 Seiten
ID (e.g. DOI, URN): 10.1002/app.43612
PPN (Catalogue-ID): WTI000897353
Note: WTI TEMA DB
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520 |a The effect of different mixing protocols in the preparation of PA6/ABS/MMA-MA (57.5/37.5/5 wt %) blends on their morphological, rheological, thermal, thermomechanical, and mechanical behavior were studied. Despite the second-phase size reduction due to copolymer incorporation, mixing sequence seems to play an important role in the properties of the blends. When PA6 is blended with the pre-blended ABS/MMA-MA system, compatibilizer is preferentially located in ABS phase and a co-continuous structure is formed. The co-continuity is believed to be responsible for the enhancements in toughness, but excessive presence of MMA-MA in ABS phase seems to hamper thermomechanical properties. On the other hand, when ABS is blended with the PA6/MMA-MA system previously prepared, compatibilizer is preferentially located in PA6 phase and a particle-in-matrix morphology is observed. The absence of excessive amount of MMA-MA in ABS phase avoids the negative effect on thermomechanical resistance, however enhancements in toughness are not so pronounced. [Copyright John Wiley & Sons. Reproduced with permission.] 
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