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Toughening and Compatibilization of Acrylonitrile–Butadiene–Styrene/Poly (Ethylene Terephthalate) Blends Using an Oxazoline-Functionalized Impact Modifier

An oxazoline-functionalized core–shell impact modifier was synthesized between aminoethanol and acrylonitrile/butadiene/styrene high rubber powder. According to the Fourier transform infrared spectroscopy test, the nitrile groups were partially converted into oxazoline groups successfully. The oxazo... Full description

Contained in: Polymer Plastics Technology and Engineering Vol. 54, No. 11 (2015), p. 1184-1192
Journal Title: Polymer Plastics Technology and Engineering
Fulltext access:
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Links: Additional Link (dx.doi.org)
ISSN: 1525-6111
Additional Keywords: ACRYLNITRIL
BUTADIEN
ELEKTRONENMIKROSKOPIE
ENDGRUPPE
FOURIER-TRANSFORM-INFRAROTSPEKTROSKOPIE
KALORIMETER
OXAZOLIN
STOFFGEMISCH
STYROL
TEREPHTHALAT
VERTRAEGLICHMACHEN
DOI: 10.1080/03602559.2014.1003225
Notes: Copyright: Metadaten: TEMA, Copyright WTI-Frankfurt eG
Copyright: (C) Alle Rechte beim Herausgeber
Physical Description: 9 Seiten, 9 Bilder, 3 Tabellen, 37 Quellen
ID (e.g. DOI, URN): 10.1080/03602559.2014.1003225
PPN (Catalogue-ID): WTI055630855
Note: WTI TEMA DB
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520 |a An oxazoline-functionalized core–shell impact modifier was synthesized between aminoethanol and acrylonitrile/butadiene/styrene high rubber powder. According to the Fourier transform infrared spectroscopy test, the nitrile groups were partially converted into oxazoline groups successfully. The oxazoline-functionalized acrylonitrile/butadiene/styrene high rubber powder was used as an impact modifier for acrylonitrile–butadiene–styrene/poly(ethylene terephthalate) blends. The differential scanning calorimeter and rheological tests demonstrated that poly(ethylene terephthalate) was partially miscible with acrylonitrile–butadiene–styrene, because the oxazoline groups of oxazoline-functionalized acrylonitrile/butadiene/styrene high rubber powder reacted with the end groups of poly(ethylene terephthalate). The results of scanning electron microscopy indicated that the morphology of acrylonitrile–butadiene–styrene/poly(ethylene terephthalate) blends with proper oxazoline-functionalized acrylonitrile/butadiene/styrene high rubber powder content was improved significantly. The best mechanical properties were achieved, When 6 wt% oxazoline-functionalized acrylonitrile/butadiene/styrene high rubber powder was added into acrylonitrile–butadiene–styrene/poly(ethylene terephthalate) blends. [Taylor & Francis Group. Reproduced with permission.] 
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