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Rotational States of Methyl Radical Monitored by EPR Line Shape of Matrix-Isolated CH $$_{3}$$ 3 in CO $$_{2}$$ 2 and N $$_{2}$$ 2 O Solids

Methyl radicals, CH $$_{3}$$ 3 , were trapped in matrices of solid CO $$_{2}$$ 2 and N $$_{2}$$ 2 O by condensing the methyl along with the matrix constituents from the gas phase. The obtained EPR spectra were analyzed using EasySpin and/ or SimFonia simulation software and ab-initio computed quantu... Full description

Contributors: Dmitriev, Yu A
Melnikov, V D
Zelenetckii, I A
Benetis, N P
Contained in: Journal of low temperature physics Dordrecht [u.a.] : Springer Vol. 185, No. 5 (2016), p. 633-640
Journal Title: Journal of low temperature physics
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Links: Volltext (dx.doi.org)
ISSN: 0022-2291
DOI: 10.1007/s10909-015-1422-7
Regional Holdings: TIB – German National Library of Science and Technology
Physikalisch-Technische Bundesanstalt
Language: English
Notes: Copyright: © Springer Science+Business Media New York 2016
ID (e.g. DOI, URN): 10.1007/s10909-015-1422-7
PPN (Catalogue-ID): OLC1987204735
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700 1 |a Dmitriev, Yu A 
700 1 |a Melnikov, V D 
700 1 |a Zelenetckii, I A 
700 1 |a Benetis, N P 
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950 |a Quantum-chemistry computation  |a Physics  |a Molecular rotation  |a Matrix isolation  |a Spectrum anisotropy  |a Electron paramagnetic resonance  |a Magnetism, Magnetic Materials  |a Condensed Matter Physics  |a Characterization and Evaluation of Materials  |2 DE-601 
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