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Influence of Strength of Atom-Wall Interactions on Adsorption Mechanism

The influence of the atom-wall interaction on adsorption in 4 nm cylindrical pores has been studied using Grand Canonical Monte Carlo simulations. A model with smooth ideal walls has been used to remove the influence of heterogeneous structures. It has been found that the layering transition pressur... Full description

Main Author: Kuchta, Bogdan
Contributors: Firlej, Lucyna | Author
Maurin, Guillaume | Author
Contained in: Adsorption : Journal of the International Adsorption Society Dordrecht [u.a.] : Springer Science + Business Media B.V Vol. 11, No. 1 (2005), p. 367-372
Journal Title: Adsorption : Journal of the International Adsorption Society
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Links: Volltext (dx.doi.org)
ISSN: 1572-8757
Additional Keywords: Monte Carlo simulations
OriginalPaper
adsorption mechanism
atom-wall interaction
nanopores
DOI: 10.1007/s10450-005-5952-1
Language: English
Physical Description: Online-Ressource
ID (e.g. DOI, URN): 10.1007/s10450-005-5952-1
s10450-005-5952-1
PPN (Catalogue-ID): SPR022297871
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520 |a The influence of the atom-wall interaction on adsorption in 4 nm cylindrical pores has been studied using Grand Canonical Monte Carlo simulations. A model with smooth ideal walls has been used to remove the influence of heterogeneous structures. It has been found that the layering transition pressures strongly depend on the atom-wall interaction. The interaction also defines the number of layers adsorbed below the capillary condensation pressure. It has been observed that the stability of adsorbed layers is modulated by the strength of the atom-wall interaction. 
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