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Subsolidus Phase Relations of the CoO x | -CuO-SrO System

The subsolidus phase relations of the CoO x-CuO-SrO system were investigated in air. The samples were equilibrated at 900 °C. The pseudo-ternary section contains three stoichiometric binary oxide phases (Sr2 CuO3, SrCuO2 and Sr14 Cu24 O41−δ) and a binary oxide solid solution: Sr6+x Co5 O15+δ(0 ≤ x ≤... Full description

Main Author: Grivel, J.-C.
Contained in: Journal of Phase Equilibria and Diffusion Boston, Mass : Springer Vol. 38, No. 5 (2017), p. 646-655
Journal Title: Journal of Phase Equilibria and Diffusion
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Links: Volltext (dx.doi.org)
ISSN: 1863-7345
Additional Keywords: OriginalPaper
experimental phase equilibria
isothermal section
oxide systems
pseudoternary
DOI: 10.1007/s11669-017-0581-4
Language: English
Physical Description: Online-Ressource
ID (e.g. DOI, URN): 10.1007/s11669-017-0581-4
s11669-017-0581-4
PPN (Catalogue-ID): SPR059680687
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520 |a The subsolidus phase relations of the CoO x-CuO-SrO system were investigated in air. The samples were equilibrated at 900 °C. The pseudo-ternary section contains three stoichiometric binary oxide phases (Sr2 CuO3, SrCuO2 and Sr14 Cu24 O41−δ) and a binary oxide solid solution: Sr6+x Co5 O15+δ(0 ≤ x ≤ 0.36). Two binary phases extend into the ternary system forming solid solutions, i.e., Sr14 Cu24−x Co x O41−δ(0 ≤ x ≤ 5) and Sr6+x Co5−y Cu y O15+δ(0 ≤ x ≤ 0.36, 0 ≤ y ≤ 1.0). The Sr6+x Co5 O15+δ solid solution was found to undergo a phase separation into a mixture of Sr6 Co5 O15−δ and Sr14 Co11 O33 upon annealing at 600 °C. This transformation is reversible. 
653 |a OriginalPaper 
653 |a experimental phase equilibria 
653 |a isothermal section 
653 |a oxide systems 
653 |a pseudoternary 
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