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Near-Infrared Responsive Liquid Crystalline Elastomers Containing Photothermal Conjugated Polymers

In this work, we report the first example of uniaxial aligned conjugated polymer (CP)/liquid crystalline elastomer (LCE) composite material by doping polyaniline nanoparticles into a classical monodomain polysiloxane-based LCE matrix. A series of comparative experiments are performed to investigate... Full description

Contained in: Macromolecules Vol. 49, No. 11 (2016), p. 4023-4030
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Links: Additional Link (dx.doi.org)
ISSN: 1520-5835
Additional Keywords: BELEUCHTUNG
ELASTOMER
KONJUGIERTES-POLYMER
NANOPARTIKEL
POLYANILIN
SILICON:POLYMER
VERGLEICHSTEST
DOI: 10.1021/acs.macromol.6b00640
Notes: Copyright: Metadaten: TEMA, Copyright WTI-Frankfurt eG
Copyright: (C) Alle Rechte beim Herausgeber
Physical Description: 8 Seiten, 61 Quellen
ID (e.g. DOI, URN): 10.1021/acs.macromol.6b00640
PPN (Catalogue-ID): WTI002391538
Note: WTI TEMA DB
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520 |a In this work, we report the first example of uniaxial aligned conjugated polymer (CP)/liquid crystalline elastomer (LCE) composite material by doping polyaniline nanoparticles into a classical monodomain polysiloxane-based LCE matrix. A series of comparative experiments are performed to investigate the photoresponsive properties of these polyaniline/LCE samples in correspondence to the two different conjugation forms (emeralidine salt (ES) or emeralidine base (EB)) and the varied doping concentrations (0.5 or 1.0 wt %) of the incorporated polyaniline nanoparticles. Taking advantage of the excellent photothermal conversion efficiency, these novel polyaniline/LCE composite materials can lift up ca. 200 times their own weights under the NIR illumination driving force, and such a photostimulated muscle-like actuation behavior is fully reversible after NIR light is removed. 
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653 4 |a ELASTOMER 
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653 4 |a BELEUCHTUNG 
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