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A robust transparent protective hard-coating material using physicochemically-incorporated silica nanoparticles and organosiloxanes

Here, we report on the synthesis of a silica nanoparticle (NP)-reinforced oligosiloxane nanohybrid material (SM-nanocomposite) and demonstrate its properties as a robust transparent hard coating material for various applications. The oligosiloxane (MMO) resin as a matrix was synthesized using methyl... Full description

Contained in: Progress in Organic Coatings. An International Journal Vol. 105 (2017), p. 330-335
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Links: Additional Link (dx.doi.org)
Additional Keywords: BESCHICHTETER-WERKSTOFF
GEL
HARTSTOFF
KOMPOSIT
KONDENSATION
NANOKRISTALLINER-VERBUNDWERKSTOFF
NANOPARTIKEL
SILICIUMDIOXID
SILICON:POLYMER
DOI: 10.1016/j.porgcoat.2017.02.004
Notes: Copyright: Metadaten: TEMA, Copyright WTI-Frankfurt eG
Copyright: (C) Alle Rechte beim Herausgeber
Physical Description: 6 Seiten, 26 Quellen
ID (e.g. DOI, URN): 10.1016/j.porgcoat.2017.02.004
PPN (Catalogue-ID): WTI00377869X
Note: WTI TEMA DB
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520 |a Here, we report on the synthesis of a silica nanoparticle (NP)-reinforced oligosiloxane nanohybrid material (SM-nanocomposite) and demonstrate its properties as a robust transparent hard coating material for various applications. The oligosiloxane (MMO) resin as a matrix was synthesized using methyl and methacryl silanes via a hydrolytic sol-gel condensation. The silica NPs with various sizes (12, 20 and 60 nm) as nanofillers were also synthesized through a hydrolytic sol-gel condensation, and the surface of NPs was organically modified with methyl and methacryl functions, which allowed stable dispersion and chemical cross-linking of the NPs with MMO matrix. In this work, we introduce synthetic steps of the nanocomposite and discuss the optical, morphological, thermal and mechanical properties of the composite. [Copyright Elsevier B.V. Reproduced with permission.] 
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