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The extended variant of the bond valence–bond length correlation curve for boron(III)–oxygen bonds

The extended variant of the bond valence (s)–bond length (r) correlation curve for boron(III)–oxygen bonds has been closely approximated using the three-parameter function s = [k/(r – l)] – m, where s is measured in valence units (vu), r is measured in Å, k = 0.53 Å·vu, l = 0.975(1) Å and m = 0.32 v... Full description

Published: München, Oldenbourg Wissenschaftsverlag, 2015
Contained in: Zeitschrift für Kristallographie - Crystalline Materials Vol. 230, No. 7 (2015), p. 495-498
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Links: Additional Link (dx.doi.org)
ISSN: 2196-7105
Additional Keywords: BOR
KORRELATION
SAUERSTOFF
WERTIGKEIT
DOI: 10.1515/zkri-2015-1847
Notes: Copyright: Metadaten: TEMA, Copyright WTI-Frankfurt eG
Copyright: (C) Alle Rechte beim Herausgeber
Physical Description: 4 Seiten, 27 Quellen
ID (e.g. DOI, URN): 10.1515/zkri-2015-1847
PPN (Catalogue-ID): WTI05529247X
Note: WTI TEMA DB
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520 |a The extended variant of the bond valence (s)–bond length (r) correlation curve for boron(III)–oxygen bonds has been closely approximated using the three-parameter function s = [k/(r – l)] – m, where s is measured in valence units (vu), r is measured in Å, k = 0.53 Å·vu, l = 0.975(1) Å and m = 0.32 vu. The function s = exp[(r0 – r)/b] traditionally used in the modern bond valence model requires the separate set of the bond valence parameters (r0 = 1.362 Å; b = 0.23 Å) in order to approximate the above s–r curve for the bonds shorter than ∼1.3 Å. [Oldenbourg Wissenschaftsverlag GmbH. Reproduced with permission.] 
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