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Direct replication of micro-nanostructures in the fabrication of superhydrophobic silicone rubber surfaces by compression molding

We describe a simple method for fabricating superhydrophobic high temperature vulcanized (HTV) silicone rubber surfaces by direct replication using a compression molding system. The resulting rubber samples possessed micro-nanostructures on the surface. This micro- and nano-scale roughness produced... Full description

Contained in: Applied Surface Science Vol. 458 (2018), p. 619-628
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Links: Additional Link (dx.doi.org)
Additional Keywords: ALUMINIUM
AUSFORMEN
FORMPRESSEN
HOCHTEMPERATUR
HYSTERESE
KONTAKTWINKEL
NANOMETERBEREICH
PRESSE:VORRICHTUNG
RAUIGKEIT
REPLIKAT
SILICON:POLYMER
SILICONKAUTSCHUK
WASSERABSTOSSENDE-EIGENSCHAFT
DOI: 10.1016/j.apsusc.2018.07.099
Notes: Copyright: Metadaten: TEMA, Copyright WTI-Frankfurt eG
Copyright: (C) Alle Rechte beim Herausgeber
Physical Description: 10 Seiten, 70 Quellen
ID (e.g. DOI, URN): 10.1016/j.apsusc.2018.07.099
PPN (Catalogue-ID): WTI061091022
Note: WTI TEMA DB
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520 |a We describe a simple method for fabricating superhydrophobic high temperature vulcanized (HTV) silicone rubber surfaces by direct replication using a compression molding system. The resulting rubber samples possessed micro-nanostructures on the surface. This micro- and nano-scale roughness produced a water contact angle of >160° and a contact angle hysteresis of <3°. The roughness patterns on chemically etched aluminum surfaces, which served as templates, were successfully replicated on the rubber surfaces. An antistiction coating applied to the template surface ensured that the rubber was completely removed during demolding and that the replicated micro-nanostructures on the silicone surface were preserved. Surface roughness of the aluminum templates was optimized at HCl concentrations of 15 wt%, with a lower roughness value observed at acid concentrations above and below this value. The developed HTV silicone rubber surfaces also demonstrated a freezing delay and a self-cleaning capacity. [Copyright Elsevier B.V. Reproduced with permission.] 
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